Solution:Diamond is a poor conductor of electricity because it does not have free electrons like metals, while graphite, another allotrope- Diamond does not conduct electricity because it has no free electrons.
Here's a more detailed explanation:
- Structure of Diamond: In a diamond, each carbon atom is covalently bonded to four other carbon atoms in a strong, three-dimensional tetrahedral network. All four valence electrons of each carbon atom are involved in forming these strong covalent bonds.
- Absence of Free Electrons: Because all the valence electrons are tightly held in these bonds, there are no electrons that are free to move throughout the crystal lattice.
- Electrical Conductivity: Electrical conductivity in a material depends on the presence of mobile charge carriers, which are usually free electrons. Since diamond lacks these free electrons, it cannot conduct electricity. It acts as an excellent electrical insulator.
In contrast, graphite, another allotrope of carbon, has a layered structure where each carbon atom is bonded to only three other carbon atoms. This leaves one valence electron per carbon atom delocalized and free to move between the layers, allowing graphite to conduct electricity.