Solution:Biogas - Biogas is a fuel gas produced from anaerobic digestion of organic matter (like cow-dung).Electrocardiography - Electrocardiography (ECG or EKG) is a medical test that detects heart problems by measuring the electrical activity of the heart.
D.D.T. DDT (dichlorodiphenyltrichloroethane) is an insecticide. Cow-dung is used for biogas production.
Nicotine - Nicotine is the addictive alkaloid naturally found in tobacco plants.
Therefore, the correctly matched pairs are 2 and 4.