Solution:The pattern followed here is :Sum of alphabetical positions of 1st and 2nd letter = 3rd letter
DGK → D(4) + G(7) = K(11)
MLY → M(13) + L(12) = Y(25)
QFW → Q(4) + F(6) = W(23)
But,
ENR → E(5) + N(14) = S(19) ≠ R(18)
Hence, "ENR" is the odd one.