Organic Chemistry A. Hydrocarbons

Total Questions: 23

1. Which one of the following is the correct sequential order in which these appeared under simulated primitive earth condition? [I.A.S. (Pre) 1994]

Correct Answer: (a) Methane, Hydrogen Cyanide, Nitrile, Amino Acid
Solution:The Miller-Urey experiment and similar theories on the origin of life. The early Earth's atmosphere was thought to be reducing, rich in gases like methane (), ammonia (), and water vapor (). Under these conditions, and with energy sources like lightning, simpler organic molecules would have formed first, progressively leading to more complex ones.

Methane () was a primary component of the early atmosphere.

Hydrogen Cyanide (HCN) is a simple, highly reactive molecule that could form from methane and ammonia. It's a key precursor in the synthesis of more complex organic molecules.

Nitrile (R-C≑N) is a functional group that can be formed from HCN and other simple molecules. It's an intermediate step.

Amino Acids are the building blocks of proteins and are more complex molecules that could have formed from simpler precursors like HCN and nitriles in the "primordial soup."

The correct sequence of their appearance under simulated primitive earth conditions is Methane, Hydrogen Cyanide, Nitrile, Amino Acid.

2. Which is the fundamental element of all organic compounds? [56th to 59th B.P.S.C. (Pre) 2015 ,U.P.U.D.A./L.D.A. (Pre) 2001]

Correct Answer: (c) Carbon
Solution:

Carbon is the fundamental element of all organic compounds (including bio-compounds). Organic compounds are a large class of chemical compounds in which one or more atoms of carbon are covalently linked to atoms of other elements, most commonly hydrogen, oxygen, or nitrogen which allows for the creation of incredibly diverse and complex molecular structures, which are the basis of all known life.

3. In all bio-compounds the most necessary fundamental element is β€” [U.P.P.C.S. (Mains) 2015]

Correct Answer: (b) Carbon
Solution:

Carbon is the fundamental element of all organic compounds (including bio-compounds). Organic compounds are a large class of chemical compounds in which one or more atoms of carbon are covalently linked to atoms of other elements, most commonly hydrogen, oxygen, or nitrogen.

4. Which one of the following sets of elements was primarily responsible for the origin of life on the Earth? [I.A.S. (Pre) 2012]

Correct Answer: (b) Carbon, Hydrogen, Nitrogen
Solution:Biologists consider that six elements were primarily responsible for the origin of life on Earth: Hydrogen, Oxygen, Carbon, Nitrogen, Phosphorus, and Sulphur. The matter within every living earthly creature mainly consists of these chemical compounds, e.g., protein, nucleic acid, carbohydrates, vitamins, hormones, etc.

5. Which one of the following is the correct sequence in increasing order of molecular weights of the hydrocarbons? [I.A.S. (Pre) 2001]

Correct Answer: (a) Methane, Ethane, Propane, and Butane
Solution:These are alkanes, which follow the general formula Cβ‚™Hβ‚‚β‚™+β‚‚

Molecular weight increases with the number of carbon atoms.

Methane (): 1 carbon atom (MW ~ 16)

Ethane (): 2 carbon atoms (MW ~ 30)

Propane (): 3 carbon atoms (MW ~ 44)

Butane (Cβ‚„H₁₀): 4 carbon atoms (MW ~ 58)

So, the increasing order of molecular weights is Methane < Ethane < Propane < Butane.

6. A hydrocarbon in which two carbon atoms are joined by a double bond is called as an: [63rd B.P.S.C. (Pre) 2017]

Correct Answer: (b) Alkene
Solution:A hydrocarbon in which two carbon atoms are joined by a double bond is called an alkene. Alkenes have the general formula Cβ‚™Hβ‚‚β‚™ . They are also known as olefins.

7. Arrange the following carbon compounds in decreasing order of their melting points: [Chhattisgarh P.C.S. (Pre) 2022]

Correct Answer: (d) Acetic acid > Chloroform > Ethanol > Methane
Solution:The correct decreasing order of melting points is:
Acetic acid (about 16.6Β°C) > Chloroform (about -63.5Β°C) > Ethanol (about -114.1Β°C) > Methane (about -182.5Β°C).

8. Which of the following gases is used in cigarette lighters? [56th to 59th B.P.S.C. (Pre) 2015]

Correct Answer: (a) Butane
Solution:Butane is a flammable hydrocarbon with the molecular formula Cβ‚„H₁₀. It is commonly used as fuel in cigarette lighters.

9. Leakage of which of the following gases had caused the Bhopal Gas Tragedy? [Uttarakhand P.C.S. (Pre) 2012]

Correct Answer: (a) Methyl isocyanate
Solution:The Bhopal Gas Tragedy resulted from an accident that occurred on the night of December 2-3, 1984. The plant released 42 tonnes of methyl isocyanate (MIC) gas, exposing more than 500,000 people to toxic gases.

10. Bhopal Gas Tragedy was caused due to the leakage of: [U.P.P.C.S. (Pre) 2017]

Correct Answer: (a) Methyl isocyanate
Solution:The Bhopal Gas Tragedy resulted from an accident that occurred on the night of December 2-3, 1984. The plant released 42 tonnes of methyl isocyanate (MIC) gas, exposing more than 500,000 people to toxic gases.