Solution:The mass of an, substance while heating remains the same however its volume increases. Thus, its density decreases. But water exhibits an anomalous expansion on cooling and contraction on heating within a specific range of temperature.
When water at 0°C is heated, it is observed that it contracts between 0°C to 4°C, ie. volume decreases and thus density increases. The volume of water is minimum at 4°C. Hence, the density of water is maximum at 4°C.