Railway Science (Chemistry-Organic Chemistry)

Total Questions: 31

1. The difference in molecular mass between two consecutive homologous series members will be: [RRC Group D 17/08/2022 (Morning)]

Correct Answer: (c) 14
Solution:

A homologous series is a collection of compounds with the same general formula that differ only in the carbon chain length.
For Example- CH₄ , C₂H₆ , C₃H₈ , etc. Characteristics-functional group of the members are same, general formula is same, have nearly identical chemical properties.

2. All the compounds of which of the following sets belong to the same homologous series? [RRC Group D 18/08/2022 (Afternoon)]

Correct Answer: (b) 𝐶₃ 𝐻₈, 𝐶₄ 𝐻₁₀, 𝐶₅𝐻₁₂
Solution:

A collection of compounds with the same general formula that differ only in the carbon chain length. Compounds in a homologous series often have a fixed set of functional groups, resulting in chemical and physical properties that are comparable. Members of Homologous series have a general method of preparation in common.
Example: Alkanes with general formula CₙH₂ₙ₊₂, alkenes with general formula CₙH₂ₙ and alkynes with general formula CnH₂ₙ₋₂ form the most basic homologous series.

3. The first and second members, respectively, of the ketone homologous series are: [RRC Group D 18/08/2022 (Afternoon)]

Correct Answer: (b) propanone, butanone
Solution:

Propanone (C₃H₆O) is the first in the Ketone homologous series because methanone (CH₂O) or ethanone cannot exist as they cannot have a secondary carbonyl group.
It has only one double bond, that is present between carbon and oxygen. The second member is Butanone (C₄H₈O). 3rd member (Pentane 3-one, C₅ H₁₀O), 4th member (Hexane-3-one, C₆H₁₂O). Ketones are used as an excellent solvent in industry.

4. Alcohols react with sodium leading to the evolution of which of the following gases? [RRC Group D 22/08/2022 (Morning)]

Correct Answer: (c) Hydrogen
Solution:

Alcohol(Ethanol, CH3CH2OH) reacts with Sodium(Na) metal to form Sodium Alkoxide(Sodium Ethoxide,𝐶₂𝐻₅ ONa) and Hydrogen Gas  (H₂).
2 CH₃CH₂OH + 2Na →2𝐶₂𝐻₅ ONa + 𝐻₂ . It shows that ethanol is acidic in 2 nature.

5. Which of the following will be the next member of the homologous series of hexene? [RRC Group D 22/08/2022 (Evening)]

Correct Answer: (d) Heptene
Solution:

Heptene (C₇H₁₄) (Alkene, CₙH₂ₙ): used as an additive in lubricants, as a catalyst, and as a surfactant. Hexene (C₆H₁₂) used as a solvent, paint thinner, and chemical reaction medium. Pentene (C₅H₁₀):
used as a pesticide, as an additive to gasoline, and in the manufacture of other chemicals. Pentane (C₅H₁₂): used in the production of polystyrene foam. Heptane (C₇H₁₆): used in laboratories as a non-polar solvent.

6. Consider the statements given below, and choose the correct answer. [RRC Group D 23/08/2022 (Evening)]

Statement I: The series of compounds in which the same functional group replaces hydrogen in the carbon chain is called homologous series. Statement II. As the molecular mass increases in a homogeneous series, physical properties show a gradual change.

Correct Answer: (c) Both the statements are true.
Solution:

Compounds in a homologous series often have a fixed set of functional groups, resulting in chemical and physical properties that are comparable.
Typical examples of Homologous series are alkanes (CₙH₂ₙ ₊ ₂) , alkyl (CₙH₂ₙ ₊ ₁), cycloalkanes (CₙH₂ₙ) and alkenes (CₙH₂ₙ), Alkyne (CₙH₂ₙ₋₂), and alcohols (CₙH₂ₙ ₊ ₁OH).

7. Which of the following is the correct structure of a benzene molecule? [RRC Group D 24/08/2022 (Morning)]

Correct Answer: (c)
Solution:

average mass 78.112 g/mol. The structure has a six-carbon ring which is represented by a hexagon and it includes 3-double bonds. The carbon atoms are represented by a corner that is bonded to other atoms. It was discovered by Michal Faraday in 1825.
Uses - Making plastics, synthetic fibers, rubber lubricants, dyes, resins, detergents, drugs and more. Derivatives of Benzene :- Phenol (C₆H₆O), Toulene (C₆H₅CH₃), Aniline (C₆H₅NH₂), Anisole (C₇H₈O), Benzaldehyde (C₇H₆O), Acetophenone (C₈H₈O), Benzoic Acid (C₇H₆O₂), Benzenesulphonic Acid (C₆H₆O₃S), Styrene (C₈H₈).

8. Which of the following compounds possesses the highest boiling point? [RRC Group D 24/08/2022 (Evening)]

Correct Answer: (b) Acetic acid
Solution:

Acetic acid (common name)/ ethanoic acid (chemical name) (CH₃COOH) - Boiling Point (118 °C). The high molecular mass of acetic acid accounts for its high boiling point.Vinegar - At least 4% acetic acid by volume.
Methane (CH₄) - The simplest alkane, and the main constituent of natural gas. BP: -161.5 °C. Ethanol (C₂H₅OH) - an alcohol, a volatile, flammable, colorless liquid with a characteristic wine-like odor and pungent taste. BP: 78.37 °C. Chloroform (CHCl₃) - a colorless, strong-smelling, dense liquid. BP: 61.2 °C.

9. Match the following: [RRC Group D 26/08/2022 (Morning)]

Correct Answer: (a) i-c, ii-a, iii-b
Solution:

Citric Acid - It is a colourless weak organic acid. It occurs naturally in citrus fruits such as lemon, Orange, Grapefruit. Acetic Acid - it is a colorless liquid organic compound which is found in vinegar. Oxalic Acid - It is a crystalline solid that dissolves in water to give colorless, acidic solutions which is found in Pepper, Spinach, Tomato.

10. Which compound can be considered as a dehydration reagent? [RRC Group D 26/08/2022 (Afternoon)]

Correct Answer: (c) concentrated sulfuric acid
Solution:

A substance that dries or removes water from a material. In chemical reactions where dehydration occurs, the reacting molecule loses a molecule of water. Examples - Sulfuric acid, concentrated phosphoric acid, hot aluminum oxide and hot ceramic.