Railway Science (Chemistry-Organic Chemistry)

Total Questions: 31

11. In which of the following groups do all the hydrocarbons NOT belong to the same homologous series? [RRC Group D 30/08/2022 (Afternoon)]

Correct Answer: (c) 𝐢𝐻₄, 𝐢₂𝐻₆, 𝐢₃𝐻₆
Solution:

CHβ‚„ (Methane), Cβ‚‚H₆ (Ethane), C₃H₆ (Propene). Homologous series is a series of compounds with similar chemical properties and some functional groups differing from the successive members by CHβ‚‚ . Carbon chains of varying lengths have been observed in organic compounds having the same general formula. Example - Homologous series of Alkanes : CHβ‚„ , Cβ‚‚H₆ , C₃Hβ‚ˆΒ  (They differ from each other by -CHβ‚‚ unit).

12. Which of the following pairs will be in the same homologous series? [RRC Group D 02/09/2022 (Afternoon)]

Correct Answer: (c) C𝐻₃ COC𝐻₃ and 𝐢₂ 𝐻₅ COC𝐻₃
Solution:

Homologous series is a series of compounds with similar chemical properties and some functional groups differing from the successive members by CHβ‚‚ . Compounds in a homologous series often have a fixed set of functional groups, resulting in chemical and physical properties that are comparable.

13. Match the following: [RRC Group D 02/09/2022 (Evening)]

Correct Answer: (a) i-b, ii-d, iii-c, iv-e, v-a
Solution:

Ethane- A colourless, odourless, gaseous hydrocarbon (compound of hydrogen and carbon), belonging to the paraffin series. It is used to produce ethylene. Benzene- It is a chemical that is a colorless or light yellow liquid at room temperature.
It is used to make plastics, resins, synthetic fibers, rubber lubricants, etc. Acetaldehyde (ethanal)- It used in the manufacturing of perfumes, drugs, acetic acid, flavouring agent, dyes, etc.
Ethylene- It appears as a colorless gas with a sweet odor and taste. It is lighter than air. It is a ripening hormone produced by the plant. Acetone- Used in nail polish remover, paint remover, and varnish remover.

14. What will be the next homologous series member of compound C₆H₁₀? [RRC Group D 05/09/2022 (Morning)]

Correct Answer: (D) C₇H₁₂
Solution:

Homologous series - a sequence of compounds with the same functional group and similar chemical properties, differ by molecular formula of CHβ‚‚ and molecular mass of 14u. So the compound of C₆H₁₀ (Cyclohexene) can be found by adding CHβ‚‚. Alkane: Carbon - carbon single bond, Alkene: at least one Carbon - carbon double bond, Alkyne: at least one Carbon - carbon triple bond.

15. What is the total number of single bonds in cyclopentane? [RRC Group D 05/09/2022 (Afternoon)]

Correct Answer: (c) 15
Solution:

Single bond - chemical bond between two atoms involving two valence electrons. Cyclopentane (also called C pentane) - highly flammable alicyclic hydrocarbon (chemical formula Cβ‚…H₁₀). It is formed by cracking cyclohexane in the presence of alumina at a high temperature and pressure. single bonds in cyclopropane (C₃H₆) - 9.

16. The total number of isomers of butane and pentane, respectively, are: [RRC Group D 05/09/2022 (Evening)]

Correct Answer: (c) 2, 3
Solution:

Chemical compounds that have identical chemical formulas but differ in properties and the arrangement of atoms in the molecule are called Isomers. Isomers of Butane (Cβ‚„H₁₀): n-butane and isobutane. Isomers of Pentane (Cβ‚…H₁₂): n-pentane, Iso-pentane and neo-pentane. Isomers of other alkanes: CHβ‚„ - 1, Cβ‚‚H₆ - 1, C₃Hβ‚ˆ - 1, C₆H₁₄ - 5, C₇H₁₆ - 9, Cβ‚ˆHβ‚β‚ˆ - 18, C₉Hβ‚‚β‚€ - 35, C₁₀Hβ‚‚β‚‚ - 75. Other isomeric pairs: Butane and 2-methylpropane, hexane and 2-ethyl pentane, etc.

17. Match the following : [RRC Group D 06/09/2022 (Morning)]

Correct Answer: (d) i-c, ii-b, iii-a
Solution:

Functional Groups - Substituent atoms or groups of atoms that are attached to specific molecules. Examples - R-COOH (Carboxylic Acid), R-COO-R’ (Ester), R-CH=O (Aldehyde), R-O-R’ (Ether), etc.

18. Which of the following is a complex mixture of hydrocarbons that occur on Earth in liquid, gaseous or solid form, that can be refined into fuel? [RRC Group D 08/09/2022 (Afternoon)]

Correct Answer: (b) Petroleum
Solution:

It is often restricted to the liquid form, commonly called crude oil. But petroleum also includes natural gas and the viscous or solid form known as bitumen, which is found in tar sands.
Bitumen - A substance produced through the distillation of crude oil, used in the construction industry, notably for roads and highways.

19. The total numbers of covalent bond in propane are [RRC Group D 08/09/2022 (Evening)]

Correct Answer: (a) 10
Solution:

Alkanes (Cβ‚™Hβ‚‚β‚™ β‚Š β‚‚) - series of compounds that contain carbon and hydrogen atoms with single covalent bonds. These are known as saturated hydrocarbons, Examples - Methane (CHβ‚„), Ethane (Cβ‚‚H₆), Propane (C₃Hβ‚ˆ), Butane (Cβ‚„H₁₀), etc. Covalent Bond - formed by the equal sharing of electrons from both participating atoms. Ionic
Bond - form between two or more atoms by the transfer of one or more electrons between atoms.

20. Which of the following members of the homologous series of alkanes has the highest melting point? [RRC Group D 08/09/2022 (Evening)]

Correct Answer: (d) 𝐢₄ 𝐻₁₀
Solution:

In organic homologous series, the higher members show the higher melting and boiling point due to the London dispersion forces. For example in the homologous series of alkanes, the boiling point of butane is higher than the boiling point of propane.