Solution:While moving left to right across a period in the periodic table, the atomic number increases. From right to left in the periodic table the atomic radius increases. Aluminium (Al, Atomic Number 13) is group 13 element, Silicon (Si, Atomic Number 14) is group 14 element, Phosphorus (P, Atomic Number 15) is group 15 element, and Sulphur (S, Atomic Number 16) is group 16 element. Therefore Aluminium has the largest sized atoms.