Solution:At 273 Kelvin (0 degree celsius), water exists in a cage-like structure in ice form. On heating, we find that molecules gain kinetic energy and this cage-like structure breaks. Due to this breaking, the volume decreases. At 277 Kelvin or (4 degree celsius), it so happens that the entire cage like structure is broken which results in decrease in volume resulting in maximum density. Therefore, the density of water is maximum at this temperature.