Solution:The correct combination of types of explosives and ions present in them includes black powder explosive, which contains K⁺, NO₃⁻, NO₂⁻, and Hₛ⁻ ions, and Tovex explosive, which contains NH₄⁺, NO₃⁻, and NMAT ions.
Black powder, also known as gunpowder, typically consists of potassium nitrate (KNO₃), charcoal, and sulphur, resulting in these ions upon combustion.
Tovex is a water gel explosive composed of ammonium nitrate (NH NO) and other ingredients, including NMAT (Nitroamine). ANFO explosive, primarily composed of ammonium nitrate and fuel oil, does not contain the ions listed in option (c).
Smokeless powder explosives do not typically contain HCO₃⁻ ions (d). Therefore, (a) and (b) are the correct combinations.