Solution:Steam at 100°C causes more severe burns than the water at the same temperature because steam provides more heat. The boiling point of water is 100 degree celsius.At this temperature, the water will begin to change from the liquid state to the gaseous state. For this change to take place, additional energy is required. In fact, every gram of liquid water requires 540 calories of heat energy to convert it to steam.
This is called the latent heat of vaporization or latent heat of steam.so while they both would exist at the same temperature the steam would have a lot more heat energy due to the addition of 540 calories per gram of heat energy that has been absorbed .This is why steam burns are worse than that water burns.